PIPages
Labs

Seokjhin Kim

Oklahoma State University, OK·Engineering

Separating chemicals that are nearly identical takes a great deal of energy in industry. One example is splitting olefins such as ethylene from paraffins such as ethane.

Fields

Engineering

Materials Science

Chemistry

Topics

membranes

gas separation

olefin/paraffin separation

Grants
1 known grant, through Jan 2028

What they work on

  1. Determine how catalytic atomic layer deposition heals molecular-scale defects in zeolitic imidazolate framework (ZIF) membranes, monitored in real time during gas separation testing.
  2. Test how growing metal oxides by ALD tunes ZIF membrane pore size and olefin/paraffin selectivity, by continuously controlling and monitoring pore size during in situ modification.
  3. Use metal ALD to introduce transition metals that interact with diffusing gases, and determine how metal electronegativity affects gas permeance and selectivity.
  4. Relate ALD processing conditions to membrane structure and separation performance using high-resolution characterization techniques.

More about the research

Membranes, thin materials that let some molecules pass while blocking others, could do this job more cheaply. But membranes face a trade-off. Large pores or defects let gas flow quickly but reduce selectivity, the ability to pass only the desired molecule. Precisely controlling pore size and defects is the key challenge.

Why it matters

More selective membranes for olefin/paraffin separation could replace energy-intensive, costly separation methods in the chemical industry. The design principles learned here could also apply to membranes for other gas, liquid, particle, and biomolecular separations. This could help industries that depend on purification and filtration.

Known grants

From NIH and NSF research grants. Labs often have other funding we can't see.

Design of Pore-engineered Membranes via in situ Atomic Layer Deposition Process for Improved Separations

NSF · Aug 2024 – Jan 2028

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The school

Oklahoma State University: 15 labs on PI Pages, $254M a year on research, 238 research doctorates a year.

More about Oklahoma State University

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