PIPages
Labs

Francis Spano

Temple University, PA·Chemistry

Most electronics run on inorganic semiconductors such as silicon. Semiconductors built from organic molecules can be cheaper to process and more flexible.

Fields

Chemistry

Physics

Materials Science

Topics

organic semiconductors

excimers

H-aggregates

Grants
1 known grant, through May 2027

What they work on

  1. Develop a Holstein-Peierls Hamiltonian model of molecular H- and J-aggregates that treats excimer formation and emission fully quantum mechanically, alongside absorption and energy transport.
  2. Use the model to explain the absorption and photoluminescence spectra of perylene diimide dimers and larger π-stacks, which form excimers to different degrees.
  3. Test whether excimers act as energy traps by analyzing density matrix equations of motion, comparing predictions with femtosecond transport measurements made by Purdue collaborators.

More about the research

They already appear in OLED displays, solar cells and wearable sensors. How well these materials perform depends on what happens after they absorb light: whether the energy is re-emitted, moved to other molecules, or lost. One problem is excimers. These are excited states shared by neighboring molecules that give off redder, weaker light. They turn electronic energy into light less efficiently and may trap energy that should be moving through the material.

Why it matters

This work could help guide the design of better organic electronics, including OLED displays, solar cells and wearable sensors. It may show how molecular packing controls excimer formation. That knowledge could suggest ways to design molecular aggregates that avoid excimers, which waste light energy and trap energy.

Known grants

From NIH and NSF research grants. Labs often have other funding we can't see.

Understanding Excimers in Molecular J- and H-aggregates: A Holstein-Peierls Approach

NSF · Jun 2023 – May 2027

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The school

Temple University: 22 labs on PI Pages, $315M a year on research, 238 research doctorates a year.

More about Temple University

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